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From: donpat3/29/2012 8:37:49 PM
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Electricity and Carbon Dioxide Used to Generate Alternative Fuel




Producing fuel from CO2 and sunlight. (Credit: Image courtesy of University of California - Los Angeles)

ScienceDaily (Mar. 29, 2012) — Imagine being able to use electricity to power your car -- even if it's not an electric vehicle. Researchers at the UCLA Henry Samueli School of Engineering and Applied Science have for the first time demonstrated a method for converting carbon dioxide into liquid fuel isobutanol using electricity.

Today, electrical energy generated by various methods is still difficult to store efficiently. Chemical batteries, hydraulic pumping and water splitting suffer from low energy-density storage or incompatibility with current transportation infrastructure.

In a study published March 30 in the journal Science, James Liao, UCLA's Ralph M. Parsons Foundation Chair in Chemical Engineering, and his team report a method for storing electrical energy as chemical energy in higher alcohols, which can be used as liquid transportation fuels.

"The current way to store electricity is with lithium ion batteries, in which the density is low, but when you store it in liquid fuel, the density could actually be very high," Liao said. "In addition, we have the potential to use electricity as transportation fuel without needing to change current infrastructure."

Liao and his team genetically engineered a lithoautotrophic microorganism known as Ralstonia eutropha H16 to produce isobutanol and 3-methyl-1-butanol in an electro-bioreactor using carbon dioxide as the sole carbon source and electricity as the sole energy input.

Photosynthesis is the process of converting light energy to chemical energy and storing it in the bonds of sugar. There are two parts to photosynthesis -- a light reaction and a dark reaction. The light reaction converts light energy to chemical energy and must take place in the light. The dark reaction, which converts CO2 to sugar, doesn't directly need light to occur.

"We've been able to separate the light reaction from the dark reaction and instead of using biological photosynthesis, we are using solar panels to convert the sunlight to electrical energy, then to a chemical intermediate, and using that to power carbon dioxide fixation to produce the fuel," Liao said. "This method could be more efficient than the biological system."

Liao explained that with biological systems, the plants used require large areas of agricultural land. However, because Liao's method does not require the light and dark reactions to take place together, solar panels, for example, can be built in the desert or on rooftops.

Theoretically, the hydrogen generated by solar electricity can drive CO2 conversion in lithoautotrophic microorganisms engineered to synthesize high-energy density liquid fuels. But the low solubility, low mass-transfer rate and the safety issues surrounding hydrogen limit the efficiency and scalability of such processes. Instead Liao's team found formic acid to be a favorable substitute and efficient energy carrier.

"Instead of using hydrogen, we use formic acid as the intermediary," Liao said. "We use electricity to generate formic acid and then use the formic acid to power the CO2 fixation in bacteria in the dark to produce isobutanol and higher alcohols."

The electrochemical formate production and the biological CO2 fixation and higher alcohol synthesis now open up the possibility of electricity-driven bioconversion of CO2 to a variety of chemicals. In addition, the transformation of formate into liquid fuel will also play an important role in the biomass refinery process, according to Liao.

"We've demonstrated the principle, and now we think we can scale up," he said. "That's our next step."
The study was funded by a grant from the U.S. Department of Energy's Advanced Research Projects Agency-Energy (ARPA-E).
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Story Source:
The above story is reprinted from materials provided by University of California - Los Angeles. The original article was written by Wileen Wong Kromhout.
Note: Materials may be edited for content and length. For further information, please contact the source cited above.
Journal Reference:
H. Li, P. H. Opgenorth, D. G. Wernick, S. Rogers, T.-Y. Wu, W. Higashide, P. Malati, Y.-X. Huo, K. M. Cho, J. C. Liao. Integrated Electromicrobial Conversion of CO2 to Higher Alcohols. Science, 2012; 335 (6076): 1596 DOI: 10.1126/science.1217643
dx.doi.org

sciencedaily.com


Science 30 March 2012:
Vol. 335 no. 6076 p. 1596
DOI: 10.1126/science.1217643

BREVIA

Integrated Electromicrobial Conversion of CO2 to Higher Alcohols

Han Li1,2, Paul H. Opgenorth3, David G. Wernick1, Steve Rogers4, Tung-Yun Wu1, Wendy Higashide4, Peter Malati5, Yi-Xin Huo4, Kwang Myung Cho4, James C. Liao1,2,3,6, *

-Author Affiliations

1Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, CA 90095, USA.
2The Molecular Biology Institute, UCLA, Los Angeles, CA 90095, USA.
3Department of Chemistry and Biochemistry, UCLA, Los Angeles, CA 90095, USA.
4Easel Biotechnologies, Los Angeles, CA 90024, USA.
5Department of Materials Science and Engineering, UCLA, Los Angeles, CA 90095, USA.
6Institute of Genomics and Proteomics, UCLA, Los Angeles, CA 90095, USA.

*To whom correspondence should be addressed. E-mail: liaoj@seas.ucla.edu

ABSTRACT
One of the major challenges in using electrical energy is the efficiency in its storage. Current methods, such as chemical batteries, hydraulic pumping, and water splitting, suffer from low energy density or incompatibility with current transportation infrastructure. Here, we report a method to store electrical energy as chemical energy in higher alcohols, which can be used as liquid transportation fuels. We genetically engineered a lithoautotrophic microorganism, Ralstonia eutropha H16, to produce isobutanol and 3-methyl-1-butanol in an electro-bioreactor using CO2 as the sole carbon source and electricity as the sole energy input. The process integrates electrochemical formate production and biological CO2 fixation and higher alcohol synthesis, opening the possibility of electricity-driven bioconversion of CO2 to commercial chemicals.

sciencemag.org
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